Cations derived formally by the addition of a
hydron or other cationic species to any position of an arene, e.g.
C6H7+
, benzenium. The term includes:
-
Arenium σ-adducts (Wheland intermediates) (which are considered to be intermediates
in electrophilic aromatic substitution reactions) and other cyclohexadienyl cations.
-
Arenium π-adducts, such as:
[σ-
adduct (sigma-
adduct), π-
adduct (pi-
adduct)].
Source:
PAC, 1995, 67, 1307
(Glossary of class names of organic compounds and reactivity intermediates based on
structure (IUPAC Recommendations 1995))
on page 1318
See also:
PAC, 1994, 66, 1077
(Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994))
on page 1077
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.
