In measurement of non-faradaic admittance (or tensammetry), a plot of
alternating current against
applied potential shows a minimum or maximum when a non-
electroactive substance undergoes
adsorption or
desorption at the surface of the
indicator electrode.
Such a maximum or minimum may be called an
apex to emphasize its non-faradaic origin and distinguish it from a '
summit', which would result from a charge-transfer process. The highest value of the current
on such an
apex may be called an
apex current, and the corresponding
applied potential may be called an
apex potential.
Source:
PAC, 1985, 57, 1491
(Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations
1985))
on page 1494
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.