Bond migration, i.e. the formal transfer of one end of a
skeletal bond to another position, with a compensating transfer of a hydrogen atom, can be indicated
by a prefix of the form
'
abeo-'.
The prefix is compiled as follows: a numeral denoting the stationary (unchanged) end
of the migrating bond (
x) is followed by parentheses enclosing the locant denoting the original position (
y) from which the other end of this bond has migrated, an arrow, and the locant (
z) denoting the new position to which the bond has moved. The closing parenthesis is
followed by the italicized prefix
abeo-(Latin: I go away) to indicate
bond migration. The original numbering is retained for the new compound and is used for the numbers
x,
y and
z. It is always necessary to specify the resulting stereochemistry.
Source:
InChI=1/C19H32/c1-18-11-5-7-16(18)15-9-8-14-6-3-4-12-19(14,2)17(15)10-13-18/h14-17H,3-13H2,1-2H3/t14-,15+,16+,17+,18+,19+/m0/s1
InChI=1/C19H32/c1-18-10-6-8-16(18)15-13-14-7-4-3-5-11-19(14,2)17(15)9-12-18/h14-17H,3-13H2,1-2H3/t14?,15-,16-,17-,18-,19-/m1/s1
InChI=1/C19H32/c1-18-10-6-8-16(18)15-13-14-7-4-3-5-11-19(14,2)17(15)9-12-18/h14-17H,3-13H2,1-2H3/t14-,15+,16+,17+,18+,19+/m0/s1
QZLYKIGBANMMBK-DOQFWFFUBB
QKULWYVBGBOWFA-FSQANUGRBM
QKULWYVBGBOWFA-DOQFWFFUBF
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.